Abstract

Research Article

Organic compositional analysis of propellant powders using monolithic material sorption extraction (MSSE)-a feasibility study

Jason W Birkett*, Ellen Goudsmits and George P Sharples

Published: 05 September, 2017 | Volume 1 - Issue 1 | Pages: 068-076

The application of monolithic material sorption extraction, specifically MonoTrapTM, to the extraction of organic gunshot residue (OGSR) compounds from unburnt propellant powders is described. Four different MonoTraps were assessed for their capability to extract OGSR compounds from two different ammunition types. Extracts were analysed using gas chromatography-mass spectrometry. Results indicated that the carbon disc was suitable for the extraction of OGSR compounds from unburnt propellant powders. Quantities for major compounds were comparable to methanol extractions. The method was successfully used to detect a wide range of OGSR compounds, including nitrotoluenes, nitroglycerin, diphenylamines and centralites and is expected to be applicable to a wide range of ammunition types.

Read Full Article HTML DOI: 10.29328/journal.jfsr.1001008 Cite this Article Read Full Article PDF

Keywords:

Forensic science; Ballistics; Propellant; MonoTrap; Chromatography

References

  1. MacCrehan WA, Bedner M. Development of a smokeless powder reference material for propellant and explosives analysis. Forensic Sci Int. 2006; 163: 119-124. Ref: https://goo.gl/2FfnS9
  2. West C, Baron G, Minet JJ. Detection of gunpowder stabilizers with ion mobility spectrometry. Forensic Sci Int. 2007; 166: 91-101. Ref: https://goo.gl/rV78qb
  3. Thomas JL, Lincoln D, McCord BR. Separation and detection of smokeless powder additives by ultra-performance liquid chromatography with tandem mass spectrometry (UPLC/MS/MS). J Forensic Sci. 2013; 58: 609-615. Ref: https://goo.gl/gFeA8U
  4. Dalby O, Birkett JW. The evaluation of solid phase micro-extraction fibre types for the analysis of organic components in unburned propellant powders. J Chromatogr A. 2010; 1217: 7183-1788. Ref: https://goo.gl/W6p3oL
  5. Joshi M, Rigsby K, Almirall JR. Analysis of the headspace composition of smokeless powders using GC-MS, GC-µECD and ion mobility spectrometry. Forensic Sci Int. 2011; 208: 29-36. Ref: https://goo.gl/UX4m2g
  6. Svec F, Tennikova TB. Historical Review, in: Svec F, Tennikova TB, Deyl Z. (Eds.) Monolithic materials: preparation, properties and applications. Elsevier Science. 2003; 1-15.
  7. Huang X, Yuan D. Preparation of stir bars for sorptive extraction based on monolithic material. J Chromatogr A. 2007; 1154: 152-157. Ref: https://goo.gl/sr4gtZ
  8. GL Sciences Inc, MonoTrapTM guide to proper use, GL Sciences Inc. 2007; 1-36.
  9. Buchmeiser MR. Polymeric monolithic materials: Syntheses, properties, functionalization and applications. Polymer. 2007; 48: 2187-2198. Ref: https://goo.gl/2AUew3
  10. Pietrzynska M, Voelkel A, Bielicka-Daszkiewicz K. Preparation and examination of monolithic inneedle extraction (MINE) device for the direct analysis of liquid samples. Anal Chim Acta. 2013; 776: 50-56. Ref: https://goo.gl/aZnDDr
  11. Namera A, Saito T. Advances in monolithic materials for sample preparation in drug and pharmaceutical analysis. Trends in Analytical Chemistry. 2013; 45: 182-196. Ref: https://goo.gl/pz1TXm
  12. Gu H, Yin D, Ren J, Zhang B, Zhang Q. Preparation of quaternary amine monolithic column for strong anion-exchange chromatography and its application to the separation of Enterovirus 71. J Chromatogr B. 2016; 399-405. Ref: https://goo.gl/P3svgk
  13. Pietrzynska M, Tomczak R, Jezierska K, Voelkel A, Jampilek J. Polymer-ceramic Monolithic InNeedle Extraction (MINE) device: Preparation and examination of drug affinity. Mater Sci Eng C. 2016; 68: 70-77. Ref: https://goo.gl/Ea9h3y
  14. Luo YB, Ma Q, Feng YQ. Stir rod sorptive extraction with monolithic polymer as coating and its application to the analysis of fluoroquinolones in honey sample. J Chromatogr A. 2010; 1217: 3583-3589. Ref: https://goo.gl/BWWGfM
  15. Luo YB, Zheng HB, Wang JX, Gao Q, Yu QW, et al. An anionic exchange stir rod sorptive extraction based on monolithic material for the extraction of non-steroidal anti-inflammatory drugs in environmental aqueous samples. Talanta. 2011; 86: 103-108. Ref: https://goo.gl/GivpBh
  16. Wang S, He Y, Wang Y, Tao N, Wu X, et al. Comparison of flavour qualities of three sourced Eriocheir sinensis. Food Chem. 2016; 200: 24-31. Ref: https://goo.gl/NJ3xbs
  17. Zhao Lm, Wu W, Tao Np, Li Yq, Wu N, et al. Characterization of important odorants in four steamed Coilia ectenes from China by gas chromatography–mass spectrometry-olfactometry. Fisheries Science, 2015; 81: 947-957. Ref: https://goo.gl/CQUQEs
  18. Ma W, Fu S, Hashi Y, Chen Z. Determination of chiral jasmonates in flowers by GC/MS after monolithic material sorptive extraction. J Agric Food Chem. 2013; 61: 6288-6292. Ref: https://goo.gl/GgK1Sf
  19. Nogueira JMF. Stir-bar sorptive extraction-15 years making sample preparation more environment friendly. TrAC. 2015; 71: 214-223. Ref: https://goo.gl/9j2Zyy
  20. Gallidabino M, Romolo FS, Bylenga K, Weyermann C. Development of a Novel Headspace Sorptive Extraction Method To Study the Aging of Volatile Compounds in Spent Handgun Cartridges. Anal Chem. 2014; 86: 4471-4478. Ref: https://goo.gl/wUDKVh
  21. Goudsmits E, Sharples GP, Birkett JW. Preliminary classification of characteristic organic gunshot residue compounds. Sci Justice. 2016; 56: 421-425. Ref: https://goo.gl/ajoJd3
  22. Goudsmits E, Sharples GP, Birkett JW. Recent trends in organic gunshot residue analysis. TrAC. 2015; 74: 46-57. Ref: https://goo.gl/pqPb13
  23. Meng H, Caddy B. Gunshot residue analysis - a review. J Forensic Sci. 1997; 42: 553-570. Ref: https://goo.gl/z6iQyG
  24. Dalby O, Butler D, Birkett JW. Analysis of gunshot residue and associated materials--a review. J Forensic Sci. 2010; 55: 924-943. Ref: https://goo.gl/s15FK1
  25. Taudte RV, Beavis A, Blanes L, Cole N, Doble P, et al. Detection of gunshot residues using mass spectrometry. Biomed Res Int. 2014; 2014: 1-16. Ref: https://goo.gl/gsN2CS
  26. Chang KH, Yew CH, Abdullah AF. Optimization of headspace solid-phase microextraction technique for extraction of volatile smokeless powder compounds in forensic applications, J Forensic Sci. 2014; 59: 1100-1108. Ref: https://goo.gl/nyJHSK
  27. Gassner AL, Weyermann C. LC-MS method development and comparison of sampling materials for the analysis of organic gunshot residues, Forensic Sci Int. 2016; 264: 47-55. Ref: https://goo.gl/mBxeut

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